Pengaruh Ukuran Partikel Zeolit Terhadap Peningkatan Kadar Bioetanol
Abstract
ABSTRACT: Background : The development of the world energy needs are increasing and limitations of fossil energy causes the current attention devoted to search for sources of environmentally friendly renewable energy such as solar energy, hydro energy, geothermal energy, and biomass energy. Global issues of climate change also encourage the use of biomass as a replacement fuel or as an additive.Objective : To determine the effect of particle size on the provision of natural zeolite and to merease levels of Bioethanol and To make bhioethanol with grading more pure than the levels of the previous samples with the addition of natural zeolite as an adsorbent of water.Methods : This study was a kind of experimental research, data analysis methods used in this study was the SPSS statistical one-way analysis of variance ( Oneway Analysis of variance = Oneway ANOVA ).Results : From the results of this study were obtained from the addition of bioethanol increased levels of zeolites with different particle size measurement, with a No. 20 sieve size levels increased by 18 %, sieve size No. 50 levels increased by 20.4 %, while there was an increase in coarse mixture levels by 7.2 %. The result the results of ANOVA test should significant any different about particle size with increasing levels of bioetanol.Conclusion : Based on the results obtained, it can be concluded that the smaller the particle size, will be produced of greater levels of bioethanol.Keywords : Elevated levels, particle size zeolite, Bioethanol . ABSTRAKSI: Latar Belakang: Perkembangan kebutuhan energi dunia yang semakin meningkat dan keterbatasan energi fosil menyebabkan perhatian saat ini ditujukan untuk mencari sumber-sumber energi terbarukan yang ramah lingkungan seperti energi surya, energi hidro, energi geotermal, dan energi biomassa. Isu global tentang perubahan iklim juga mendorong penggunaan energi biomasa sebagai pengganti bahan bakar atau sebagai bahan aditif.  Tujuan: Untuk mengetahui pengaruh ukuran partikel pemberian Zeolit alam terhadap peningkatan kadar Bioetanol dan untuk membuat Bioetanol dengan kadar yang lebih murni dari kadar sampel sebelumnya dengan penambahan zeolit alam sebagai adsorbent air.Metode: Penelitian ini merupakan jenis penelitian eksperimental, metode analisis data yang digunakan pada penelitian ini adalah data statistik SPSS analisis ragam satu arah (Oneway Analysis of variance = Oneway ANOVA)Hasil: Dari penelitian ini diperoleh hasil peningkatan kadar bioetanol dari penambahan zeolit dengan ukuran ukuran partikel yang berbeda, dengan ukuran ayakan No 20 terjadi peningkatan kadar sebesar 18 %, ukuran ayakan No 50 terjadi peningkatan kadar sebesar 20,4 % sedangkan pada campuran kasar terjadi peningkatan kadar sebesar 7,2 %. Dari hasil uji ANOVA diperoleh hasil yang signifikan.Kesimpulan: Berdasarkan hasil yang diperoleh, maka dapat disimpulkan bahwa semakin kecil ukuran partikelnya maka semakin besar kadar bioetanol yang di hasilkanKata Kunci: Peningkatan kadar, Ukuran partikel Zeolit, Bioetanol.References
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[27] Senda, S.P., Saputra, H., Sholeh, A., Rosjidi, M., Mustafa, A., 2006, Prospek Aplikasi Produk Berbasis Zeolit untuk Slow Release Substances (SRS) dan Membran, Artikel Badan Pengkajian dan Penerapan Teknologi Indonesia, ISSN 1410-9891.
[28] Sheppard, R. A. and Gude, A.J.. 1969. Chemical Composition and Physical Properties of The Related Zeolites Offretite and Erionite. American Mineralogist: 54: 875-886.
[29] Smith, J.M. Chemical Engineering Kinetics. McGraw-Hill Book Co, Singapura. 1967.
[30] Suardana, I.N., 2008, Optimalisasi Daya Adsorpsi Zeolit Terhadap Ion Kromium(III),Jurnal Penelitian dan Pengembangan Sains & Humaniora Lembaga PenelitianUndiksha, Vol. 2(1), 17-33.
[31] Sumin, L., Youguang, M.A., Chunying, Z., Shuhua, S., Qing, H.E., 2009, The Effect of Hydrophobic Modification of Zeolites on CO2 Absorption Enhancement,Chinese Journal of Chemical Engineering, 17(1), 36-41.
[32] Suwardi. 2000. Pemanfaatan mineral zeolit di bidang pertanian dan lingkungan [abstrak]. Di dalam : Seminar Staf Jurusan Tanah, Fakultas Pertanian, IPB, 22 Maret 2000. http://suwardi-abstrak.blogspot.com. [26 Mei 2009].
[33] Ulku, S., Cakicioglu, F., 1991, Energy Recovery in Drying Application, Renewable Energy, 1 No. 5/6, 695-698.
[34] Van Bekkum, H, E.M Flaningen, and J.C. Jansen, Introduction to Zeolite Science and Practice. New York : Elsevier.USA. 2007.
[35] Yuarini D.A.A. 2007. Proses Produksi Dan Karakteristik Arak di Kecamatan Sidemen, Kabupaten Karangasem, Propinsi Bali. Skrpisi S1 Fakultas Teknologi Pertanian.Universitas Udayana. Bali
[36] [IUPAC] International of Pure and Applied Chemistry. 1997. IUPAC Compendium of Chemical Terminology. Ed ke-2. http://www.iupac.org/ goldbook.pdf. ( 5 mei 2014).
[2] Al-Asheh S, Banat F, Al-Lagtah N. 2004. Separation of Ethanol-Water Mixtures Using Molecular Sieves and Biobased Adsorbents. Chem Eng Res Des 82 : 855-864.
[3] Auerbach, Scott M., Carrado, Kathleen A., & Dutta, Prabir K.. 2003. Handbook of zeolite science and technology. New York: Marcel Dekker, Inc.
[4] Balat, M., Balat, H. and Öz, C., 2008, Progress in bioethanol processing. Progress in Energy and Combustion Science, 34:551–573.
[5] Bries. A. Rodiel, 2008. The Extraction of Bioethanol from Pineaplle (Ananas Comosus) Peelings Through Simultaneous Saccharification and Fermentation Using The Yeast Saccharomyces Cerevisiae. Quezon City Science High School, Istanbul.
[6] Butland, T.D., 2008, Adsorption Removal of Tertiary Butyl Alcohol from Wastewater by Zeolite, Thesis of Worcester Polytechnic Institute.
[7] Chemiawan. T. 2007. Krisis energi dan globalisasi http://mahasiswanegarawan. wordpress. com 18 -08 –2007 Diakses tanggal 19 maret 2014
[8] Clark J. 2007. Pembuatan Alkohol dalam Skala Produksi. http://www.chem-is-try.org. (5 mei 2014).
[9] Depkes,1979. Farmakope indonesia edisi III. Jakarta: Depatermen kesehatan Republik Indonesia.
[10] Djaeni, M., 2008, Energy Efficient Multistage Zeolite Drying for Heat Sensitive
[11] Dwi, 2007. Bioetanol, energi alternatif yang kompetitif. www. Dwi blogspot.com.Tanggal 19 marat 2014
[12] Flanigen EM. 1980. Molecular Sieve Zeolite Technology-The First Twenty-Five Years. Plenary Paper-Technology. Pure Appl Chem 52 : 2191-2211. Great Britain : Pergamon Pr.
[13] Fogler, Scott H. Elements of Chemical Reaction Engineering . University of Michigan, USA. 1991.
[14] Gruszkiewics, M.S., Simonson, J.M., Burchell, T.D., Cole, D.R., 2005, Water Adsorption and Desorption on Microporous Solids at Elevated Temperature, Journal of Thermal Analysis and Calorimetry 81, 609-615.
[15] Harjanto, S., (1987) : Lempung, Zeolit, Dolomit, dan Magnesit, Publikasi khusus,Direktorat Sumber Daya Mineral, 108-119.
[16] Igbokwe, P.K., Okolomike, R.O., Nwokolo, S.O., 2008, Zeolite for Drying of Ethanol-Water and Methanol-Water Systems from Nigerian Clay Resource, Journal of The University of Chemical Technology and Metallurgy, 43, I, 109-112.
[17] Jozefaciuk, G., Bowanko, G., 2002, Effect of Acid and Alkali Treatments on Surface Areas and Adsorption Energies of Selected Minerals, Journal Clays and Clay Minerals, 50 No. 6, 771-783.
[18] Kohl S. 2004. Ethanol 101-7 : Dehidration. Ethanol Today. Maret 2004. http://www.ovsclub.com.vn/datapic/File/Ethanol_Dehydration.pdf. (5 mei 2014).
[19] Moechtar., (1990), “Farmasi Fisikaâ€, UGM Press, Yogyakarta, 169
[20] Onuki S. 2006. Bioethanol : Industrial production process and recent studies. www.public.iastate.edu/~tge/courses/ce521/sonuki.pdf. (5 mei 2014).
[21] Ozkan, F.C., Ulku, S., 2005, The Effect of HCl Treatment on Water Vapor Adsorption Characteristics of Clinoptilolite Rich Natural Zeolite, Journal Microporous and Mesoporous Materials 77, 47-53.
[22] Ozkan, F.C., Ulku, S., 2008, Diffusion Mechanism of Water Vapour in A Zeolitic Tuff Rich in Clinoptilolite, Journal of Thermal Analysis and Calorimetry 94, 699-702
[23] Paturau, J. M. 1981. By Product of the Sugar Cane Sugar Industry: An Introduction to Their Industrial Utilization. Elseiver Scientific Publ. Co.Amsterdam.
[24] Payra, P., Dutta, P.K., 2003, Zeolites : A Primer, in Auerbach, S.M., Carrado, K.A.,Dutta, P.K.,(Ed.). Handbook of Zeolite Science and Technology, Marcel Dekker New York, pp 1-19.
[25] Riyadi, Awang .2007. Pemanasan Global dan Konsep Rumah Hemat Energi. www.Google.com.tanggal 19 maret 20014
[26] Rosita, N., Erawati, T., Moegihardjo, M., 2004, Pengaruh Perbedaan Metode Aktivasi Terhadap Efektivitas Zeolit sebagai Adsorben, Majalah Farmasi Airlangga, 4 No. 1, 20-25.
[27] Senda, S.P., Saputra, H., Sholeh, A., Rosjidi, M., Mustafa, A., 2006, Prospek Aplikasi Produk Berbasis Zeolit untuk Slow Release Substances (SRS) dan Membran, Artikel Badan Pengkajian dan Penerapan Teknologi Indonesia, ISSN 1410-9891.
[28] Sheppard, R. A. and Gude, A.J.. 1969. Chemical Composition and Physical Properties of The Related Zeolites Offretite and Erionite. American Mineralogist: 54: 875-886.
[29] Smith, J.M. Chemical Engineering Kinetics. McGraw-Hill Book Co, Singapura. 1967.
[30] Suardana, I.N., 2008, Optimalisasi Daya Adsorpsi Zeolit Terhadap Ion Kromium(III),Jurnal Penelitian dan Pengembangan Sains & Humaniora Lembaga PenelitianUndiksha, Vol. 2(1), 17-33.
[31] Sumin, L., Youguang, M.A., Chunying, Z., Shuhua, S., Qing, H.E., 2009, The Effect of Hydrophobic Modification of Zeolites on CO2 Absorption Enhancement,Chinese Journal of Chemical Engineering, 17(1), 36-41.
[32] Suwardi. 2000. Pemanfaatan mineral zeolit di bidang pertanian dan lingkungan [abstrak]. Di dalam : Seminar Staf Jurusan Tanah, Fakultas Pertanian, IPB, 22 Maret 2000. http://suwardi-abstrak.blogspot.com. [26 Mei 2009].
[33] Ulku, S., Cakicioglu, F., 1991, Energy Recovery in Drying Application, Renewable Energy, 1 No. 5/6, 695-698.
[34] Van Bekkum, H, E.M Flaningen, and J.C. Jansen, Introduction to Zeolite Science and Practice. New York : Elsevier.USA. 2007.
[35] Yuarini D.A.A. 2007. Proses Produksi Dan Karakteristik Arak di Kecamatan Sidemen, Kabupaten Karangasem, Propinsi Bali. Skrpisi S1 Fakultas Teknologi Pertanian.Universitas Udayana. Bali
[36] [IUPAC] International of Pure and Applied Chemistry. 1997. IUPAC Compendium of Chemical Terminology. Ed ke-2. http://www.iupac.org/ goldbook.pdf. ( 5 mei 2014).
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Published
2013-04-04
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Wulandari, R. and Priyono, C. (2013) “Pengaruh Ukuran Partikel Zeolit Terhadap Peningkatan Kadar Bioetanol”, Indonesian Journal on Medical Science, 1(2). Available at: http://ejournal.poltekkesbhaktimulia.ac.id/index.php/ijms/article/view/34 (Accessed: 5 April 2025).
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